Role of Mixed Oxides in Hydrogen Production through the Dry Reforming of Methane over Nickel Catalysts Supported on Modified γ-Al2O3

نویسندگان

چکیده

H2 production through dry reforming of methane (DRM) is a hot topic amidst growing environmental and atom-economy concerns. Loading Ni-based reducible mixed oxide systems onto thermally stable support reliable approach for obtaining catalysts good dispersion high stability. Herein, NiO was dispersed over MOx-modified-γ-Al2O3 (M = Ti, Mo, Si, or W; x 2 3) incipient wetness impregnation followed by calcination. The obtained catalyst were characterized infrared, ultraviolet–visible, X-ray photoelectron spectroscopies, temperature-programmed reduction. mentioned synthetic procedure afforded the proper nucleation different NiO-containing oxides and/or interacting-NiO species. With modifiers, interaction with γ-Al2O3 found to change, Ni2+ environment reformed exclusively, tendency species undergo reduction modified greatly. Catalyst 5Ni3MAl W) comprised variety species, whereby interacted modifier (e.g., NiSiO3, NiAl2O4, NiWO3). These two displayed equal efficiency, >70% yield at 800 °C, up 420 min on stream. 5Ni3SiAl regained nearly all its activity during regeneration cycles.

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ژورنال

عنوان ژورنال: Processes

سال: 2021

ISSN: ['2227-9717']

DOI: https://doi.org/10.3390/pr9010157